Monday, June 27, 2011

Ferromagnetic Materials

There are a number of crystalline materials that exhibit ferromagnetism (or ferrimagnetism). The table on the right lists a representative selection of them, along with their Curie temperatures, the temperature above which they cease to exhibit spontaneous magnetization (see below).

Ferromagnetism is a property not just of the chemical makeup of a material, but of its crystalline structure and microscopic organization. There are ferromagnetic metal alloys whose constituents are not themselves ferromagnetic, called Heusler alloys, named after Fritz Heusler. Conversely there are nonmagnetic alloys, such as types of stainless steel, composed almost exclusively of ferromagnetic metals.

One can also make amorphous (non-crystalline) ferromagnetic metallic alloys by very rapid quenching (cooling) of a liquid alloy. These have the advantage that their properties are nearly isotropic (not aligned along a crystal axis); this results in low coercivity, low hysteresis loss, high permeability, and high electrical resistivity. A typical such material is a transition metal-metalloid alloy, made from about 80% transition metal (usually Fe, Co, or Ni) and a metalloid component (B, C, Si, P, or Al) that lowers the melting point.
A relatively new class of exceptionally strong ferromagnetic materials are the rare-earth magnets. They contain lanthanide elements that are known for their ability to carry large magnetic moments in well-localized f-orbitals.

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